Stratospheric influences on the tropospheric seasonal cycles of nitrous oxide and chlorofluorocarbons

Abstract

The stratospheric influence on the tropospheric cycles of N 2O, CFC-11 (CC13F), CFC-I2 (CC1 2F2) and CFC-113 (CC12FCC1F 2) is investigated using observations from the AGAGE global trace gas monitoring network and the results of the Whole Atmosphere Community Climate Model (WACCM). WACCM provides the basis for a number of predictions about the relative amplitudes of N2O and CFC seasonal cycles and about the relative magnitude and phasing of seasonal cycles in the northern and southern hemispheres. These predictions are generally consistent with observations, suggesting that the stratosphere exerts a coherent influence on the tropospheric seasonal cycles of trace gases whose primary sinks are in the stratosphere. This stratospheric influence may complicate efforts to validate estimated source distributions of N20, an important greenhouse gas, in atmospheric transport model studies. Copyright 2004 by the American Geophysical Union.