Abstract
The structure and reactions of acyl t-alkyl nitroxides are summarised. Intramolecular reactions of nitroxides in this class are reported, and their intramolecular reactivities are expressed as EM-values by comparison with suitable intermolecular models. The results, which may be representative of free radical reactions in general, suggest that intramolecular additions are likely to have EM-values several orders of magnitude greater than intramolecular hydrogen atom transfer. This parallels observations in ionic chemistry. © 1990 De Gruyter
Cite
CITATION STYLE
Perkins, M. J., Berti, C., Brooks, D. J., Grierson, L., Grimes, J. A. M., Jenkins, T. C., & Smith, S. L. (1990). Acyl nitroxides: Reactions and reactivity. Pure and Applied Chemistry, 62(2), 195–200. https://doi.org/10.1351/pac199062020195
Register to see more suggestions
Mendeley helps you to discover research relevant for your work.
