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Do fluorescence and transient absorption probe the same intramolecular charge transfer state of 4-(dimethylamino)benzonitrile?

Journal of Chemical Physics (2009) 131(3)
DOI: 10.1063/1.3173609
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Abstract

We present here the results of time-resolved absorption and emission experiments for 4-(dimethylamino)benzonitrile in solution, which suggest that the fluorescent intramolecular charge transfer (ICT) state may differ from the twisted ICT (TICT) state observed in transient absorption. © 2009 American Institute of Physics.

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Gustavsson, T., Coto, P. B., Serrano-Andŕs, L., Fujiwara, T., & Lim, E. C. (2009). Do fluorescence and transient absorption probe the same intramolecular charge transfer state of 4-(dimethylamino)benzonitrile? Journal of Chemical Physics, 131(3). https://doi.org/10.1063/1.3173609

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