Gas Evolution and Stability of Alkali-Activated MSWI Slag and Fly Ash: Implications for Safe Use and Energy Valorization

Abstract

This study investigates the valorization of municipal solid waste incineration (MSWI) residues—specifically bottom ash with slag (BA + S) and fly ash (FA)—through alkaline activation in geopolymer and cementitious systems. The research demonstrates that alkali activation significantly improves mechanical properties, with compressive strengths up to 45.9 MPa for cement mortars and 33.2 MPa for geopolymers. A key innovation includes the quantification of hydrogen gas release during activation, with up to 72.5 dm3/kg H2 from BA + S, offering insights into binder design and potential green hydrogen recovery. Environmental leachability assessments confirmed that activated BA + S immobilizes heavy metals effectively, although FA showed higher barium and lead leaching. Morphological analysis (SEM, granulometry) revealed microstructural changes enhancing reactivity. Additionally, a practical swelling test is proposed for early detection of expansion risk. The findings contribute to the development of sustainable, high-performance binders from waste, with implications for circular economy and energy valorization strategies.