Mechanisms of chloride and sulfate removal from municipal-solid-waste-incineration fly ash (MSWI FA): Effect of acid-base solutions

Abstract

A general approach to managing municipal solid waste is by incineration. Unfortunately, large amounts of municipal-solid-waste-incineration fly ash (MSWI FA) is produced in the process, with their heavy metals content posing further problems to the environment. One fundamental treatment of MSWI FA heavy metals is called solidification-stabilization, where MSWI FA is solidified in cement-based materials to cap hazardous elements from being released into the environment. Mortar formed from this cement mixed with MSWI FA suffer from decreased compressive strength due to their chloride and sulfate contents. Thus, pre-treatment of MSWI FA to remove these salts before producing mortar is desirable. This study investigated treating MSWI FA with deionized water, 0.01 M and 0.1 M nitric acid, and 0.1 M and 0.25 M sodium carbonate to remove chloride and sulfate. Physical and chemical structures of treated and untreated MSWI FA was studied to understand the chloride and sulfate removal mechanisms. Treated MSWI FA was used as cement replacement in mortar, and the compressive strength was tested. Results suggest that all of the treatment solutions tested in this study can equally remove chloride (around 250,000 mg/kg), but sodium carbonate can remove sulfate at the highest extent (15,821 mg/kg). In addition, mortar with deionized-water-treated MSWI FA gave the highest compressive strength. Heavy metals leaching was tested by the Toxicity Characterization Leaching Procedure (TCLP) method, with results passing the standard.