Abstract
A simple, convenient and efficient synthetic approach to highly substituted pyrroles has been developed by utilizing a gold(III)-catalyzed tandem amination-intramolecular hydroamination reaction. The first examples of gold-catalyzed, selective amination of 1-en-4-yn-3-ols have also been disclosed. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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Shu, X. Z., Liu, X. Y., Xiao, H. Q., Ji, K. G., Guo, L. N., & Liang, Y. M. (2008). Tandem gold(III)-catalyzed amination-intramolecular hydroamination reactions of 1-En-4-yn-3-ols with sulfonamides: Efficient approach to highly substituted pyrroles. Advanced Synthesis and Catalysis, 350(2), 243–248. https://doi.org/10.1002/adsc.200700452
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