Synthesis and structure of [Na4(DMSO)15][(I 3)3(I)]. Self-assembly of hexacoordinated sodium

Álvaro Duarte-Ruiz; Nelson Nuñez-Dallos; Luis Garzón-Tovar; Klaus Wurst; Eliseo Avella-Moreno; Fernando Gómez-Baquero

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Synthesis and structure of [Na4(DMSO)15][(I 3)3(I)]. Self-assembly of hexacoordinated sodium

Chemical Communications (2011) 47(25) 7110-7112

DOI: 10.1039/c1cc11898f

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Abstract

A new complex with the molecular formula [Na4(DMSO) 15][(I3)3(I)] represents the first example of Na+ coordinated solely by DMSO. The triiodide (I3-) and iodide (I-) anions form an infinite linear chain running throughout the crystal. © 2011 The Royal Society of Chemistry.

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Duarte-Ruiz, Á., Nuñez-Dallos, N., Garzón-Tovar, L., Wurst, K., Avella-Moreno, E., & Gómez-Baquero, F. (2011). Synthesis and structure of [Na4(DMSO)15][(I 3)3(I)]. Self-assembly of hexacoordinated sodium. Chemical Communications, 47(25), 7110–7112. https://doi.org/10.1039/c1cc11898f

Synthesis and structure of [Na4(DMSO)15][(I 3)3(I)]. Self-assembly of hexacoordinated sodium

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