Oxygen reduction reaction catalyzed by nickel complexes based on thiophosphorylated calix[4]resorcinols and immobilized in the membrane electrode assembly of fuel cells

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Abstract

The catalytic activity of the nickel complexes of thiophosphorylated calix[4]resorcinols for oxygen reduction in a polymer electrolyte membrane fuel cell (PEMFC) has been studied. The conformation of the macrocyclic ligand determines the morphology and catalytic properties of the resulting organometallic species.

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Kadirov, M. K., Knyazeva, I. R., Nizameev, I. R., Safiullin, R. A., Matveeva, V. I., Kholin, K. V., … Sinyashin, O. G. (2016). Oxygen reduction reaction catalyzed by nickel complexes based on thiophosphorylated calix[4]resorcinols and immobilized in the membrane electrode assembly of fuel cells. Dalton Transactions, 45(41), 16157–16161. https://doi.org/10.1039/c6dt02881k

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