Corrosion behavior and adsorption thermodynamics of some Schiff bases on mild steel corrosion in industrial water medium

Abstract

The inhibition performance and adsorption behavior of (E)-2-(3- nitrobenzylidene) hydrazine carbothioamide (SB1) and (E)-2-(4-(dimethylamino) benzylidene) hydrazine carbothioamide (SB2) on mild steel corrosion in industrial water medium have been investigated by gravimetric, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The results revealed that inhibition efficiency depends on both the concentration of the inhibitors and temperature of the system. Increasing temperature reduces the inhibition efficiency of both inhibitors. Polarization studies indicated that these compounds behave as mixed type of inhibitors. The adsorption of both inhibitors was spontaneous and followed Langmuir adsorption isotherm. Thermodynamic parameters are calculated and discussed. The relation between inhibition efficiency and molecular structures of SB1 and SB2 was discussed by considering quantum chemical parameters. The surface adsorbed film was characterized by scanning electron microscopy (SEM). © 2013 S. S. Shivakumar and K. N. Mohana.