An oxygen-deficient perovskite as selective catalyst in the oxidation of alkyl benzenes

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Abstract

Extraordinary reaction rates and selectivity for the conversion of alkyl aromatic compounds, such as p-xylene, in terephthalic acid were observed for a heterogeneous perovskite catalyst of composition (La,Sr)0.5(Mn,Co) 0.5O2.38 (see picture). The oxygen-deficient catalyst was prepared by reduction of the oxygen-stoichiometric parent compound. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Aguadero, A., Falcon, H., Campos-Martin, J. M., Al-Zahrani, S. M., Fierro, J. L. G., & Alonso, J. A. (2011). An oxygen-deficient perovskite as selective catalyst in the oxidation of alkyl benzenes. Angewandte Chemie - International Edition, 50(29), 6557–6561. https://doi.org/10.1002/anie.201007941

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