Long-Term Creep Compliance of Wood Polymer Composites: Using Untreated Wood Fibers as a Filler in Recycled and Neat Polypropylene Matrix

Abstract

Neat (NPP) and recycled (RPP) polypropylene matrix materials were used to prepare wood–polymer composites with untreated wood fibers up to 40 wt.%. Long-term creep properties obtained through the time-temperature superposition showed superior creep resistance of composites with NPP matrix. In part, this is attributed to their higher crystallinity and better interfacial adhesion caused by the formation of a transcrystalline layer. This difference resulted in up to 25% creep compliance reduction of composites with NPP matrix compared to composites with recycled (RPP) polypropylene matrix, which does not form a transcrystalline layer between the fibers and polymer matrix. Despite the overall inferior creep performance of composites with RPP matrix, from the 20 wt.% on, the creep compliance is comparable and even surpasses the creep performance of unfilled NPP matrix and can be a promising way to promote sustainability.