Effects of low temperatures and high strain rates on the tensile properties of polyurethane polymers for adhesives

Abstract

The mechanical properties of polyurethane compounds were experimentally investigated by changing the composition of their components. Polyol components (polyoxypropylene glycol: PPG, polyoxytetramethylene glycol: PTMG, and polycarbonatediol: PCD) were mixed with monomeric methylene diphenyl diisocyanate to synthesize polyurethane pre-polymer, mixed with chain extenders (1,4’-butanediol: 1,4’-BD or dimethylthiotoluene diamine: DMTDA), and cured, to prepare four types of polyurethane resins. Tensile tests were conducted using a mechanical testing machine with a strain rate of approximately 0.3 s−1 and a hydraulic high-speed tensile testing machine with a strain rate of approximately 500 s−1. The temperature was controlled to be −40°C, −10°C, or 25°C. When PTMG was used as the polyol, the stress-strain relationship was less sensitive to temperatures and loading rates, and the material properties exhibited a relatively good balance between elongation and strength. Additionally, the use of 1,4’-BD as a chain extender resulted in higher elongation and lower strength than the use of DMTDA. Conversely, the stress-strain relationship was dramatically altered by the test conditions when PPG and PCD were used as the polyol and embrittlement under a combination of low temperature and high strain rate was confirmed. Furthermore, there were certain compositional combinations that exhibit necking at low temperatures.