Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN3-Ru Pincer Complex

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Abstract

A well-defined PN3-Ru pincer complex (5) bearing a redox-active bipyridine ligand with an aminophosphine arm has been established as an effective and stable molecular electrocatalyst for CO2 reduction to CO and HCOOH with negligible formation of H2 in a H2O/MeCN mixture. Done in a pince: A PN3-Ru pincer complex (see figure) has been found to show high activity and stability as a molecular electrocatalyst for CO2 reduction to CO and HCOOH in MeCN/H2O.

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Min, S., Rasul, S., Li, H., Grills, D. C., Takanabe, K., Li, L. J., & Huang, K. W. (2016). Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN3-Ru Pincer Complex. ChemPlusChem, 81(2), 166–171. https://doi.org/10.1002/cplu.201500474

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