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Synthesis, Solid-State Structure, and Bonding Analysis of a Homoleptic Beryllium Azide

Angewandte Chemie - International Edition (2017) 56(29) 8559-8563
DOI: 10.1002/anie.201703147
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Abstract

[Ph4P]2[Be(N3)4] (1) and [PNP]2[Be(N3)4] (2; PNP=Ph3PNPPh3) were synthesized by reacting Be(N3)2 with [Ph4P]N3 and [PNP]N3. Compound 1 represents the first structurally characterized homoleptic beryllium azide. The electronic structure and bonding situation in the tetraazidoberyllate dianion [Be(N3)4]2− were investigated by quantum-chemical calculations (NPA, ELF, LOL).

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Naglav, D., Tobey, B., Lyhs, B., Römer, B., Bläser, D., Wölper, C., … Schulz, S. (2017). Synthesis, Solid-State Structure, and Bonding Analysis of a Homoleptic Beryllium Azide. Angewandte Chemie - International Edition, 56(29), 8559–8563. https://doi.org/10.1002/anie.201703147

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