Improved green coffee oil antioxidant activity for cosmetical purpose by spray drying microencapsulation

Abstract

The oil extracted by cold pressing unroasted coffee beans, known as green coffee oil, has been widelyused for cosmetic purposes. The objective of this work was to prepare and characterize microcapsulescontaining green coffee oil and to verify its antioxidant activity under the effect of light, heat and oxygen. The encapsulating material was arabic gum and the microcapsules were obtained by spray drying an oil-in-water emulsion containing green coffee oil. The characterization of the microcapsules was performedby laser diffraction, scanning electron microscopy, differential scanning calorimetry and the antioxidantactivity. The antioxidant activity was determined by a modified active oxygen method with light irradia-tion, heating and oxygen flux. The microparticles were effectively produced by the proposed spray dryingmethod, which resulted in green coffee oil loads of 10 and 30%. The morphological evaluation of micro-capsules showed spherical shape with smooth and non-porous surfaces, demonstrating the adequacy ofarabic gum as encapsulating material. Calorimetric analysis of individual components and microcapsuleswith 10 and 30% green coffee oil showed diminished degradation temperatures and enthalpy, suggest-ing a possible interaction between arabic gum and green coffee oil. The antioxidant activities for puregreen coffee oil and its microcapsules with loads of 10 and 30% showed high activity when comparedto the reference antioxidant alfa-tocopherol. Microcapsules containing 10 and 30% of oil showed 7-foldand 3-fold increase in antioxidant activity when compared to pure green coffee oil. The new method forantioxidant activity determination proposed here, which applies heat, light and oxygen simultaneously, suggests a high improvement in encapsulated green coffee oil when compared to this active alone. Theresults showed herein indicate a promising industrial application of this microencapsulated green coffeeoil.