Photothermal Effect and Phase Transition in VO2 Enhanced by Plasmonic Particles

Abstract

Phase change metasurfaces based on VO2, which are pre-heated with electric current and optically addressed by projected structured light hologram, are considered to become a new paradigm in programmed THz/middle IR flat optics. Macroscopic quasi-homogeneous arrays of Au nanoparticles show large near IR absorption and a significant photothermal effect capable of boosting a light-triggered switching of VO2 and are to be carefully examined. We propose a new approach to simultaneously probe the altered temperature and electric conductivity of a hybrid Au particle-VO2 film composite by monitoring a phase shift and attenuating a surface acoustic wave in a YX128° cut LiNbO3 substrate. The method shows a temperature resolution of 0.1 °C comparable with the best existing techniques for studying nanoobjects and surfaces. The laser-induced photothermal effects were characterized in a macroscopic array of Au nanostars (AuNSts) with different surface coverage. In a monolayer of 10 nm Au, coupled plasmonic nanoparticles were deposited on the LiNbO3 substrate. An optically triggered insulator-metal transition assisted by photothermal effect in AuNSts/VO2/TiO2/LiNbO3 composites was studied at varied light power. We believe that the proposed SAW-based method is of significant importance for the characterization and optimization of radiation absorbing or/and electrically heated elements of metasurfaces and other devices for lab-on-chip and optical communication/processor technology.