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Isolation and spontaneous resolution of eight-coordinate stereoisomers

Angewandte Chemie - International Edition (1999) 38(15) 2199-2201
DOI: 10.1002/(SICI)1521-3773(19990802)38:15<2199::AID-ANIE2199>3.0.CO;2-S
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Abstract

The right- and left-handed propeller-shaped enantiomers of the eight- coordinate SmI2 complexes shown can be resolved by crystallization from dimethoxyethane (dme) at ambient temperature. Apart from representing a new type of chiral metal complex, such enantiomers are potential reagents for enantioselective reductions.

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Håkansson, M., Vestergren, M., Gustafsson, B., & Hilmersson, G. (1999). Isolation and spontaneous resolution of eight-coordinate stereoisomers. Angewandte Chemie - International Edition, 38(15), 2199–2201. https://doi.org/10.1002/(SICI)1521-3773(19990802)38:15<2199::AID-ANIE2199>3.0.CO;2-S

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