The synthesis and characterization of rare-earth fluocarbonates

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Abstract

A procedure is described for synthesizing cerium fluorcarbonate. This synthetic bastnaesite was characterized through X-Ray diffraction, chemical analysis and thermogravimetric studies. The solubility product of Ce-bastnaesite was determined to be 10-10.1. The stability constant pK CeHCO32+complex was experimentally determined to be 3.04 ± 0.21. Based on the thermodynamic data available in the literature, a speciation diagram has been prepared for the synthetic cerium bastnaesite. © 2013 Hosokawa Powder Technology Foundation.

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Pradip, P., Li, C. C. H., & Fuerstenau, D. W. (2012). The synthesis and characterization of rare-earth fluocarbonates. KONA Powder and Particle Journal, 30, 193–200. https://doi.org/10.14356/kona.2013018

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