Neutral iodotriazole foldamers as tetradentate halogen bonding anion receptors

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Abstract

Neutral tetradentate halogen bond donor foldamers were synthesised and exhibit enhanced anion affinities over their hydrogen bonding analogues, displaying iodide selectivity over lighter halide, carboxylate and dihydrogen phosphate anions. A foldamer with a chiral (S)-binaphthol motif was demonstrated to distinguish between enantiomers of chiral anions.

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Borissov, A., Lim, J. Y. C., Brown, A., Christensen, K. E., Thompson, A. L., Smith, M. D., & Beer, P. D. (2017). Neutral iodotriazole foldamers as tetradentate halogen bonding anion receptors. Chemical Communications, 53(16), 2483–2486. https://doi.org/10.1039/c7cc00727b

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