Supramolecular Diiodine-Bromostannate(IV) Complexes: Narrow Bandgap Semiconductors

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Abstract

Three supramolecular bromostannates(IV) with “trapped” diiodine molecules, Cat2{[SnBr6](I2)} (Cat = Me4N+ (1), 1-MePy+ (2) and 4-MePyH (3)), were synthesized. In all cases, I2 linkers are con-nected with bromide ligands via halogen···halogen non-covalent interactions. Articles 1–3 were studied using Raman spectroscopy, thermogravimetric analysis, and diffuse reflectance spectroscopy. The latter indicates that 1–3 are narrow band gap semiconductors.

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Korobeynikov, N. A., Usoltsev, A. N., Abramov, P. A., Sokolov, M. N., & Adonin, S. A. (2022). Supramolecular Diiodine-Bromostannate(IV) Complexes: Narrow Bandgap Semiconductors. Molecules, 27(12). https://doi.org/10.3390/molecules27123859

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