Impact of High Fe Doping on Structure, Optical, and Magnetic Properties of Zinc Oxide Nanostructures Synthesized by Hydrothermal Route

Abstract

Zn1−xFexO nanocomposites (NCs) with varying Fe concentrations (x = 0, 0.1, 0.2, 0.3, and 0.4) were effectively prepared using the hydrothermal approach, and their morphology, structural, optical, and magnetic properties were systematically analyzed. XRD analysis confirmed Fe doping reduced crystallinity and crystallite size. TEM images of Zn1−xFexO NCs exhibited smaller and more agglomerated nanostructures compared to the pure ZnO NPs. Raman and XPS analyses indicated increased lattice disorder, oxygen vacancies, and the coexistence of Fe2+/Fe3+ species. UV–Vis spectra showed enhanced visible light absorption and a tunable band gap, while PL results reflected defect-induced emission shifts and quenching, associated with zinc vacancies, interstitials, and oxygen-related defects. Magnetic measurements revealed a transition from diamagnetism to ferromagnetic-like behavior at room temperature for Fe content x ≥ 0.2, with magnetization strongly dependent on doping level. These results highlight Zn1−xFexO for advanced optoelectronic and spintronic applications.