Triphenyltellurium chloride

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Abstract

The asymmetric unit of the title compound, C18H 15ClTe, contains two molecules which are in inverted orientations. The compound displays a tetrahedral geometry around the Te atom in spite of there being five electron domains. This is attributed to the fact that the lone pair is not sterically active. The dihedral angles between the three phenyl rings are 76.51(16)/73.75(16)/71.06(17) and 78.60(17)/77.67(16)/79.11(16)° in the two molecules. The crystal packing features eight C-H..π interactions.

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Chopra, A., Jain, S., Srivastava, S. K., Gupta, S. K., & Butcher, R. J. (2014). Triphenyltellurium chloride. Acta Crystallographica Section E: Structure Reports Online, 70(4). https://doi.org/10.1107/S160053681400498X

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