Crystal structure of bis(μ2-azido)-tetrakis(triphenylphosphine)-di-silver(I)

Abstract

The title comple (PPh3)2Ag(μ-N3) 2Ag (PPh32 has been synthesized and structurally characterized by single-crystal X-ray diffraction. The silver atoms are joined through a double μ1,3-azido (N3) bridge. To each silver atom are also coordinated two P atoms from two triphenylphosphine molecules. The coordinated polyhedron around silver is a distorted tetrahedron. 2006 © The Japan Society for Analytical Chemistry.