Abstract
(Chemical Equation Presented) Stable and semiconducting: Polyanionic hydrides represent a new class of main-group-metal hydrides with unforeseen hydrogen-coordination environments. The hydrogen atom in SrAlSiH is attached exclusively to Al and forms part of a layered [AlHSi]2- polyanion (see figure). This material is the first narrow bandgap semiconductor hydride and combines the high thermal stability of saline hydrides with the air and moisture stability of interstitial transition-metal hydrides. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
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Björling, T., Noréus, D., Jansson, K., Andersson, M., Leonova, E., Edén, M., … Häussermann, U. (2005). SrAlSiH: A polyanionic semiconductor hydride. Angewandte Chemie - International Edition, 44(44), 7269–7273. https://doi.org/10.1002/anie.200502090
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