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Oxacycle synthesis via intramolecular reaction of carbanions and peroxides

Journal of the American Chemical Society (2014) 136(16) 5821-5823
DOI: 10.1021/ja5026276
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Abstract

The intramolecular reaction of dialkyl peroxides with carbanions, generated via chemoselective metal-heteroatom exchange or deprotonation, provides a new approach to cyclic ethers. Applied in tandem with C-C bond formation, the strategy enables a one-step annelation to form oxaospirocycles. © 2014 American Chemical Society.

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APA

Willand-Charnley, R., Puffer, B. W., & Dussault, P. H. (2014). Oxacycle synthesis via intramolecular reaction of carbanions and peroxides. Journal of the American Chemical Society, 136(16), 5821–5823. https://doi.org/10.1021/ja5026276

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