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[BO2]− as a Synthon for the Generation of Boron-Centered Carbamate and Carboxylate Isosteres

Angewandte Chemie - International Edition (2020) 59(32) 13628-13632
DOI: 10.1002/anie.202005674
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Abstract

Oxoborane carbamate and carboxylate analogues result from the in situ trapping of [BO2]− produced by elimination of 2,3-dimethyl-2-butene from a pinacolatoboryl anion.

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Pécharman, A. F., Hill, M. S., McMullin, C. L., & Mahon, M. F. (2020). [BO2]− as a Synthon for the Generation of Boron-Centered Carbamate and Carboxylate Isosteres. Angewandte Chemie - International Edition, 59(32), 13628–13632. https://doi.org/10.1002/anie.202005674

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