Homocoupling of benzyl halides catalyzed by POCOP-nickel pincer complexes

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Abstract

Two types of POCOP-nickel(II) pincer complexes were prepared by mixing POCOP pincer ligands and NiX 2 in toluene at reflux. The resulting nickel complexes efficiently catalyze the homocoupling reactions of benzyl halides in the presence of zinc. The coupled products were obtained in excellent to quantitative yields. © 2012 Elsevier Ltd. All rights reserved.

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Chen, T., Yang, L., Li, L., & Huang, K. W. (2012). Homocoupling of benzyl halides catalyzed by POCOP-nickel pincer complexes. Tetrahedron, 68(31), 6152–6157. https://doi.org/10.1016/j.tet.2012.05.075

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