Synthesis of hyperbranched polymer using slow monomer addition method

Abstract

This paper details the synthesis of a well-defined hyperbranched polymer using a slow monomer addition method. The polymerization under slow monomer addition conditions results in a very low monomer concentration actually present in the reaction mixture, and the exclusive reaction of the monomer with the growing polyfunctional macromolecules occurs, resulting in a high molecular weight and a high degree of branching value. Thus, the slow monomer addition is a versatile and preferential method for the controlled synthesis of a well-defined hyperbranched polymer with both a high molecular weight and a high degree of branching value. © 2012 Toshifumi Satoh.