Influence of crustal dust and sea spray supermicron particle concentrations and acidity on inorganic NO3− Aerosol during the 2013 Southern Oxidant and Aerosol Study

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Abstract

Inorganic aerosol composition was measured in the southeastern United States, a region that exhibits high aerosol mass loading during the summer, as part of the 2013 Southern Oxidant and Aerosol Study (SOAS) campaign. Measurements using a Monitor for AeRosols and GAses (MARGA) revealed two periods of high aerosol nitrate (NO3−) concentrations during the campaign. These periods of high nitrate were correlated with increased concentrations of supermicron crustal and sea spray aerosol species, particularly Na+ and Ca2+, and with a shift towards aerosol with larger (1 to 2.5 1/4m) diameters. We suggest this nitrate aerosol forms by multiphase reactions of HNO3 and particles, reactions that are facilitated by transport of crustal dust and sea spray aerosol from a source within the United States. The observed high aerosol acidity prevents the formation of NH4NO3, the inorganic nitrogen species often dominant in fine-mode aerosol at higher pH. Calculation of the rate of the heterogeneous uptake of HNO3 on mineral aerosol supports the conclusion that aerosol NO3− is produced primarily by this process, and is likely limited by the availability of mineral cation-containing aerosol surface area. Modeling of NO3− and HNO3 by thermodynamic equilibrium models (ISORROPIA II and E-AIM) reveals the importance of including mineral cations in the southeastern United States to accurately balance ion species and predict gas-aerosol phase partitioning.

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Allen, H. M., Draper, D. C., Ayres, B. R., Ault, A., Bondy, A., Takahama, S., … Fry, J. L. (2015). Influence of crustal dust and sea spray supermicron particle concentrations and acidity on inorganic NO3− Aerosol during the 2013 Southern Oxidant and Aerosol Study. Atmospheric Chemistry and Physics, 15(18), 10669–10685. https://doi.org/10.5194/acp-15-10669-2015

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