A new organometallic heteropolytungstate related to [Sb2W 22O74(OH)2]12-: Synthesis and structural characterisation of the bis-{Ru(p-cymene)}2+-containing anion [Sb2W20O70{Ru(p-cymene)} 2]10-

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Abstract

The easy synthesis of [Sb2W20O70{Ru(p- cymene)}2]10- by the reaction between the organometallic precursor [Ru(p-cymene)Cl2]2 and [Sb2W 20O70]14-, formed in situ, confirms the importance of the organometallic route to well defined ruthenium(+II)- substituted heteropolytungstates. © The Royal Society of Chemistry 2005.

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Laurencin, D., Villanneau, R., Herson, P., Thouvenot, R., Jeannin, Y., & Proust, A. (2005). A new organometallic heteropolytungstate related to [Sb2W 22O74(OH)2]12-: Synthesis and structural characterisation of the bis-{Ru(p-cymene)}2+-containing anion [Sb2W20O70{Ru(p-cymene)} 2]10-. Chemical Communications, (44), 5524–5526. https://doi.org/10.1039/b510300b

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