Bis{μ-2-[(pyridin-2-yl)imino-meth-yl]phenolato}bis-[(2-formyl-phenolato) copper(II)]

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Abstract

The asymmetric unit of the title compound, [Cu2(C 12H9N2O)2(C7H 5O2)2], contains two independent (2-formyl-phen-olato){2-[(pyridin-2-yl)imino-meth-yl]phenolato}copper(II) mol-ecules that form pseudocentrosymmetric dimers via inter-actions between the Cu and pyridyl N atoms of independent monomers. The square-planar geometry of the Cu atoms in the monomer thus becomes square-based pyramidal in the dimer. The crystal studied was an inversion twin, with unequal populations of 0.353 (17) and 0.647 (17).

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Chang, H. C., Cole, J. M., Lin, T. C., Sylvester, S. O., & Waddell, P. G. (2011). Bis{μ-2-[(pyridin-2-yl)imino-meth-yl]phenolato}bis-[(2-formyl-phenolato) copper(II)]. Acta Crystallographica Section E: Structure Reports Online, 67(6). https://doi.org/10.1107/S1600536811015674

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