Behavior of 238 pu-doped ceramics based on cubic zirconia and pyrochlore under radiation damage

Abstract

Crystalline ceramics based on durable actinide host phases such as cubic zirconia and titanate pyrochlore have been suggested for the immobilization of weapons grade plutonium and actinide wastes. Samples of crystalline ceramic based on the gadolinia-stabilized cubic zirconia, (Zr, Gd, Pu)O2, structure doped with 9.9 wt.% 238Pu were synthesized and characterized in comparison with samples of pyrochlore-based ceramic, (Ca, Gd, Hf, U, Pu)2Ti2O7, doped with 8.7 wt.% 238Pu. It was found that a resistance of cubic zirconia to self-irradiation is much higher than that of pyrochlore. At the cumulative dose l.lx1025alpha decays/m3, cubic zirconia retained its crystalline structure. No swelling or cracking were observed in the ceramic matrix. At the same cumulative dose the titanate pyrochlore became nearly amorphous and the density decreased by approximately 10 % in comparison with the initial, unaltered sample. Under self-irradiation, both ceramics demonstrated an increase of normalized Pu mass loss in deionized water depending on cumulative doses, but this increase is significantly greater for the pyrochlore-based ceramic. © 2002 Atomic Energy Society of Japan.