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A Convenient Method for the Preparation of S -Esters of Thio Analogs of Malonic Acid

  • Imamoto T
  • Kodera M
  • Yokoyama M
Bulletin of the Chemical Society of Japan (1982) 55(7) 2303-2304
DOI: 10.1246/bcsj.55.2303
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Abstract

2-Carboxyethanethioic S-esters(RSCOCH2COOH) and propanebis(thioic) S,S′-diesters (RSCOCH2COSR) were easily prepared in high yields by the direct condensation of malonic acid with thiols in the presence of ethyl polyphosphate (PPE).

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Imamoto, T., Kodera, M., & Yokoyama, M. (1982). A Convenient Method for the Preparation of S -Esters of Thio Analogs of Malonic Acid. Bulletin of the Chemical Society of Japan, 55(7), 2303–2304. https://doi.org/10.1246/bcsj.55.2303

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