Intermolecular radical carboaminohydroxylation of olefins with aryl diazonium salts and TEMPO

Abstract

Highly reactive aryl radicals can selectively be reacted with a broad variety of activated and nonactivated olefinic substrates in the presence of nitroxyl radicals. Direct recombination of the aryl radical and the nitroxide as well as telomerization of the olefin is successfully suppressed by the reaction conditions. © 2007 American Chemical Society.