Solvent extraction of cobalt and nickel by organophosphorus acids I. Comparison of phosphoric, phosphonic and phosphonic acid systems

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Abstract

The solvent extraction of cobalt(II) and nickel(II) by xylene solutions of commercial dialkyl-phosphoric (D2EHPA), phosphonic (Shell RD 577) and phosphinic acids (Cyanex CNX) has been investigated. In each case, cobalt is extracted at lower pH values than nickel; under comparable conditions, the cobalt-nickel separation increases in the order phosphoric < phosphonic

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Preston, J. S. (1982). Solvent extraction of cobalt and nickel by organophosphorus acids I. Comparison of phosphoric, phosphonic and phosphonic acid systems. Hydrometallurgy, 9(2), 115–133. https://doi.org/10.1016/0304-386X(82)90012-3

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