Fast and Versatile Pathway in Fabrication of Polyelectrolyte Multilayer Nanofiltration Membrane with Tunable Properties

Abstract

Thin film composite nanofiltration (NF) membranes are relatively new membranes compared to other types of pressure-driven membranes. However, they attract interest from researchers due to their versatility to be used in various applications. In this work, a new class of NF membrane was successfully fabricated through spin-assisted layer-by-layer assembly by depositing alternate layers of branched polyethylenimine (PEI) and poly(sodium 4-styrenesulfonate) (PSS) on ultrafiltration polysulfone (PSF) membrane. The suitability of the fabricated membranes for removal of divalent ions was investigated. It was found that the membrane consisting of (PEI/PSS)10-0.05 M NaCl showed MgCl2 rejection rate of 93.95% and permeation flux of 0.9 L/m2·h bar during tests performed using a crossflow permeation cell at a crossflow velocity of 0.65 m/s, MgCl2 feed concentration of 6530 ppm, pressure of 10 bar, temperature of 32.5°C, and pH of 6.5. This result suggests that this new fabrication method is suitable for producing polyelectrolyte multilayered (PEM) NF membranes that exhibit comparable membrane performance to commercial ones.