Abstract
Silica-supported titanium(IV) chloride is readily reduced by Mashima and co-workers' reagent (1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene) to afford materials active in ethylene polymerisation without need of aluminum alkyl cocatalyst. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Popoff, N., Espinas, J., Gouré, E., Boyron, O., Le Roux, E., Basset, J. M., … Taoufik, M. (2011). Shifting from Ziegler-Natta to Philips-type catalyst? A simple and safe access to reduced titanium systems for ethylene polymerization. Macromolecular Rapid Communications, 32(23), 1921–1924. https://doi.org/10.1002/marc.201100477
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