Abstract
Generalized hydrodynamic moment hierarchies are derived which explicitly include nonequilibrium two-particle and higher-order correlations. The approach is adapted to strongly correlated media and nonequilibrium processes on short time scales which necessitate an explicit treatment of time-evolving correlations. Closure conditions for the extended moment hierarchies are formulated by a maximum-entropy approach, generalizing related closure procedures for kinetic equations. A self-consistent set of nonperturbative dynamical equations are thus obtained for a chosen set of single-particle and two-particle (and possibly higher-order) moments. Analytical results are derived for generalized Gaussian closures including the dynamic pair distribution function and a two-particle correction to the current density. The maximum-entropy closure conditions are found to involve the Kirkwood superposition approximation. © 2012 American Institute of Physics.
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CITATION STYLE
Hughes, K. H., & Burghardt, I. (2012). Maximum-entropy closure of hydrodynamic moment hierarchies including correlations. Journal of Chemical Physics, 136(21). https://doi.org/10.1063/1.4720568
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