The 1,3-migration of phosphorus from oxygen to carbon: A new synthesis of β-ketophosphonates from enol phosphates

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Abstract

Enol phosphates, readily prepared from ketone enolates and dialkyl phosphorochloridate, can be converted to the analogous β-ketophosphonates by treatment with strong base. © 1986.

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Hammond, G. B., Calogeropoulou, T., & Wiemer, D. F. (1986). The 1,3-migration of phosphorus from oxygen to carbon: A new synthesis of β-ketophosphonates from enol phosphates. Tetrahedron Letters, 27(36), 4265–4268. https://doi.org/10.1016/S0040-4039(00)94248-5

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