A Ni(i)Fe(ii) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases

Carlo U. Perotto; George Marshall; Graham J. Jones; E. Stephen Davies; William Lewis; Jonathan McMaster; Martin Schröder

Journal ArticleOPEN ACCESS

A Ni(i)Fe(ii) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases

Chemical Communications (2015) 51(95) 16988-16991

DOI: 10.1039/c5cc05881c

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Abstract

[Ni(L1)Fe(tBuNC)4](PF6)2 is a robust NiIIFeII complex that undergoes a reversible one-electron reduction. Spectroscopic and theoretical studies show that [Ni(L1)Fe(tBuNC)4]+ is an unprecedented NiIFeII species that reproduces the electronic configuration of the Ni-L state of the [NiFe] hydrogenases.

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Perotto, C. U., Marshall, G., Jones, G. J., Stephen Davies, E., Lewis, W., McMaster, J., & Schröder, M. (2015). A Ni(i)Fe(ii) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases. Chemical Communications, 51(95), 16988–16991. https://doi.org/10.1039/c5cc05881c

A Ni(i)Fe(ii) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases

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