Abstract
Thermal analysis was applied to determine liquidus temperatures in the CsCl-PbCl2-PbO system, with the PbO concentration ranging from 0 to 20 mol%. The temperature dependence of the PbO solubility in the CsCl-PbCl2 eutectic melt was studied, and the thermodynamic parameters of the PbO dissolution were calculated. The type, morphology, and composition of oxychloride ionic groupings in the melt were determined in situ using Raman spectroscopy.
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Arkhipov, P. A., Zakiryanova, I. D., Kholkina, A. S., Bausheva, A. V., & Khudorozhkova, A. O. (2015). Phase equilibria and interaction between the CsCl-PbCl2-PbO system components. Zeitschrift Fur Naturforschung - Section A Journal of Physical Sciences, 70(10), 851–858. https://doi.org/10.1515/zna-2015-0273
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