Partial Methylation of Benzyl 4-O-Methyl-beta-D-Xylopyranoside.

  • Garegg P
  • Rasmussen S
  • Hirvisalo E
  • et al.
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Abstract

Thin layer chromatography has been used for the quantitative separation of the components obtained on the partial methylation of benzyl 4-0-methyl-jS-D-xylopyranoside. From the \ranalytical figures obtained, the relative rates of methylation of the hydroxyl groups at C-2 hydroxyl group the reactivity at the C-3 hydroxyl group increased 3.0 times. Methylation at the C-3 hydroxyl group did not affect the reactivity at the C-2 hydroxyl group.

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Garegg, P. J., Rasmussen, S. E., Hirvisalo, E. L., Munch-Petersen, J., & Munch-Petersen, J. (1963). Partial Methylation of Benzyl 4-O-Methyl-beta-D-Xylopyranoside. Acta Chemica Scandinavica, 17, 1343–1347. https://doi.org/10.3891/acta.chem.scand.17-1343

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