Rotaxane-encapsulation enhances the stability of an azo dye, in solution and when bonded to cellulose

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Abstract

A "cyclodextrin coat" dramatically enhances the stability of an azo dye towards reductive bleaching, oxidative bleaching, and photo-bleaching as is demonstrated by the rotaxane 1. This compound is obtained as single isomer in high yield from the amine-substituted dye and trichlorotriazine in water in the presence of the cyclodextrin.

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Craig, M. R., Hutchings, M. G., Claridge, T. D. W., & Anderson, H. L. (2001). Rotaxane-encapsulation enhances the stability of an azo dye, in solution and when bonded to cellulose. Angewandte Chemie - International Edition, 40(6), 1071–1074. https://doi.org/10.1002/1521-3773(20010316)40:6<1071::AID-ANIE10710>3.0.CO;2-5

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