Abstract
A sound synthetic procedure for the preparation of trans-[PtBr(µ-Br)(PPh3)]2 is described. The species was fully characterized and used to obtain [PtBr2(PPh3)(L)] complexes (L = DMSO, p-toluidine, pyridine) by a bridge-splitting reaction. All products were fully characterized by NMR spectroscopy, together with cis-[PtBr2(PPh3)(NCCH3)], obtained as an intermediate in the synthesis of the dinuclear precursor. Cis-[PtBr2(PPh3)(NCCH3)] was also studied by X-ray diffraction.
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Fioco, D., Belli Dell’Amico, D., Labella, L., Marchetti, F., & Samaritani, S. (2019). A Sound Sequence to Triphenylphosphino Dibromoplatinum(II) Complexes – Solvothermal Preparation of trans-[PtBr(µ-Br)(PPh3)]2. European Journal of Inorganic Chemistry, 2019(36), 3970–3974. https://doi.org/10.1002/ejic.201900711
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