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Curved Nanographenes as Stoppers in a [2]Rotaxane with Two-Photon Excited Emission

Journal of Organic Chemistry (2024) 89(13) 9344-9351
DOI: 10.1021/acs.joc.4c00486
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Abstract

Heptagon-containing distorted nanographenes are used as stoppers for the capping of a [2]rotaxane through a Michael-type addition reaction to vinyl sulfone groups. These curved aromatics are bulky enough to prevent the disassembly of the rotaxane but also give emissive and nonlinear (two-photon absorption and emission) optical properties to the structure.

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APA

Codesal, M. D., David, A. H. G., Santos, C. I. M., Álvaro-Martins, M. J., Maçôas, E., Campaña, A. G., & Blanco, V. (2024). Curved Nanographenes as Stoppers in a [2]Rotaxane with Two-Photon Excited Emission. Journal of Organic Chemistry, 89(13), 9344–9351. https://doi.org/10.1021/acs.joc.4c00486

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