Assessing the Environmental Situation for Excretion Management Stations in Al – Qayyarah Refinery

Abstract

‫ﺍﻟﻤﺠﻠﺩ‬ ،‫ﺍﻟﺭﺍﻓﺩﻴﻥ‬ ‫ﻋﻠﻭﻡ‬ ‫ﻤﺠﻠﺔ‬ 28 ‫ﺍﻟﻌﺩﺩ‬ ، 2 ‫ﺹ‬ ،‫ﺍﻟﻜﻴﻤﻴﺎﺀ‬ ‫ﻟﻌﻠﻭﻡ‬ ‫ﺍﻟﺜﺎﻟﺙ‬ ‫ﺍﻟﻌﻠﻤﻲ‬ ‫ﺒﺎﻟﻤﺅﺘﻤﺭ‬ ‫ﺨﺎﺹ‬ ‫ﻋﺩﺩ‬ 8-22 ، 2018-8 ‫ﺍﻟﻘﻴﺎﺭﺓ‬ ‫ﻤﺼﻔﻰ‬ ‫ﻟﻤﻁﺭﻭﺤﺎﺕ‬ ‫ﺍﻟﻤﻌﺎﻟﺠﺔ‬ ‫ﻟﻤﺤﻁﺎﺕ‬ ‫ﺍﻟﺒﻴﺌﻲ‬ ‫ﺍﻟﻭﺍﻗﻊ‬ ‫ﺘﻘﻴﻴﻡ‬ ‫ﺍﻟﺸﺎﻜﺭ‬ ‫ﻤﺠﻴﺩ‬ ‫ﻴﺴﺭﻯ‬ ‫ﺍ‬ ‫ﻤﻨﺔ‬ ‫ﻤﺤﻤ‬ ‫ﺒﺎﺴل‬ ‫ﺩ‬ ‫ﻋﻠ‬ ‫ﻗﺴﻡ‬ ‫ﻭ‬ ‫ﺍﻟﺒﻴﺌﺔ‬ ‫ﻡ‬ / ‫ﻭﺘﻘﺎﻨﺎﺘﻬﺎ‬ ‫ﺍﻟﺒﻴﺌﺔ‬ ‫ﻋﻠﻭﻡ‬ ‫ﻜﻠﻴﺔ‬ / ‫ﺍﻟﻤﻭﺼل‬ ‫ﺠﺎﻤﻌﺔ‬) ‫ﹸﺴﺘﻠﻡ‬ ‫ﺍ‬ 22 / 9 / 2018 ‫؛‬ ‫ﹸﺒل‬ ‫ﻗ‬ 25 / 10 / 2018 (‫ﺍﻟ‬ ‫ﻤﻠ‬ ‫ﺨﺹ‬ ‫ﻤﺤﻁﺔ‬ ‫ﻜﻔﺎﺀﺓ‬ ‫ﺘﻘﻴﻴﻡ‬ ‫ﺍﻟﺩﺭﺍﺴﺔ‬ ‫ﺘﻀﻤﻨﺕ‬ ‫ﻤﻌﺎﻟﺠﺔ‬ ‫ﺍﻟﻘﻴﺎﺭﺓ‬ ‫ﻤﺼﻔﻰ‬ ‫ﻤﻁﺭﻭﺤﺎﺕ‬ / ‫ﺍﻟﻌﺭﺍﻕ‬ ‫ﺘﻘ‬ ‫ﺍﻟﺘﻲ‬ ‫ﻊ‬ ‫ﺒﺎﻻﺘﺠﺎﻩ‬ ‫ﺍﻟﻘﻴﺎﺭﺓ‬ ‫ﻨﺎﺤﻴﺔ‬ ‫ﻓﻲ‬ ،‫ﺍﻟﻤﻭﺼل‬ ‫ﻟﻤﺩﻴﻨﺔ‬ ‫ﺍﻟﺸﺭﻗﻲ‬ ‫ﺍﻟﺠﻨﻭﺒﻲ‬ ‫ﻭﻷﺠل‬ ‫ﺸﻬﺭﻴﺔ‬ ‫ﻋﻴﻨﺎﺕ‬ ‫ﺠﻤﻊ‬ ‫ﺘﻡ‬ ‫ﺫﻟﻙ‬ ‫ﻭﻟﻤﺩﺓ‬ ‫ﺨﻤﺴﺔ‬ ‫ﺍﻻﻭل‬ ‫ﺘﺸﺭﻴﻥ‬ ‫ﺸﻬﺭ‬ ‫ﻤﻥ‬ ‫ﺍﺸﻬﺭ‬ 2013 ‫ﻭﻟﻐﺎﻴﺔ‬ ‫ﺸﺒﺎﻁ‬ ‫ﺸﻬﺭ‬ 2014 ‫ﻭﺍﻟﻜﻴﻤﻴﺎﺌﻴﺔ‬ ‫ﺍﻟﻔﻴﺯﻴﺎﺌﻴﺔ‬ ‫ﺍﻟﻔﺤﻭﺼﺎﺕ‬ ‫ﻤﻥ‬ ‫ﺍﻟﻌﺩﻴﺩ‬ ‫ﻋﻠﻴﻬﺎ‬ ‫ﻭﺍﺠﺭﻴﺕ‬ ‫ﻭﺍﻟﺒﺎﻴﻭﻟﻭﺠﻴﺔ‬ ‫ﺸﻤﻠ‬ ‫ﻭﺍﻟﺘﻲ‬ ‫ﺍﻟﻜﻬﺭﺒﺎﺌﻲ‬ ‫ﺍﻟﺘﻭﺼﻴل‬ ‫ﺕ‬ ، ‫ﺍﻟﺼ‬ ‫ﺍﻟﻤﻭﺍﺩ‬ ‫ﺍﻟﺫﺍﺌﺒﺔ‬ ‫ﻠﺒﺔ‬ ‫ﺍﻟﻜﻠﻴﺔ‬ ‫ﺍﻟﻌﺴﺭﺓ‬ ،‫ﺍﻟﻜﺩﺭﺓ‬ ، ، ‫ﺍﻟﺤﺎﻤﻀﻴﺔ‬ ‫ﺍﻟﺩﺍﻟﺔ‬ ،‫ﻭﺍﻟﺒﻭﺘﺎﺴﻴﻭﻡ‬ ‫ﺍﻟﺼﻭﺩﻴﻭﻡ‬ ‫ﺍﻴﻭﻨﺎﺕ‬ ،‫ﺍﻟﻜﺒﺭﻴﺘﺎﺕ‬ ،‫ﺍﻟﻔﻭﺴﻔﺎﺕ‬ ،‫ﺍﻟﻨﺘﺭﺍﺕ‬ ، ،‫ﺍﻟﺜﻘﻴﻠﺔ‬ ‫ﺍﻟﻤﻌﺎﺩﻥ‬ ،‫ﺍﻟﺩﻫﻨﻴﺔ‬ ‫ﻭﺍﻟﻤﺭﻜﺒﺎﺕ‬ ‫ﺍﻟﺯﻴﻭﺕ‬ ‫ﺍﻟﻤﺘﻁﻠﺏ‬ ‫ﺍﻟﻜﻴﻤﺎﻭﻱ‬ ‫ﻟﻸﻭﻜﺴﺠﻴﻥ‬ ‫ﹰ‬ ‫ﻓﻀﻼ‬ ‫ﻟﻠﺒﻜﺘﺭﻴﺎ‬ ‫ﺍﻟﻜﻠﻲ‬ ‫ﺍﻟﻌﺩﺩ‬ ‫ﻗﻴﺎﺱ‬ ‫ﻋﻥ‬. ‫ﻨﺘﺎﺌﺞ‬ ‫ﺍﻅﻬﺭﺕ‬ ‫ﻭﺍﻀﺤﺔ‬ ‫ﺘﻐﺎﻴﺭﺍﺕ‬ ‫ﻭﺠﻭﺩ‬ ‫ﺍﻟﺩﺭﺍﺴﺔ‬ ‫ﻗﻴﻡ‬ ‫ﻓﻲ‬ ‫ﻗﺒل‬ ‫ﺍﻋﻼﻩ‬ ‫ﺍﻟﻤﺘﻐﻴﺭﺍﺕ‬ ‫ﺍﻟﻤﻌﺎﻟﺠﺔ‬ ‫ﻋﻤﻠﻴﺔ‬ ‫ﻭﺒﻌﺩﻫﺎ‬ ‫ﻋﻤﻠﻴﺔ‬ ‫ﻗﺒل‬ ‫ﺍﻟﺤﺎﻤﻀﻴﺔ‬ ‫ﺍﻟﺩﺍﻟﺔ‬ ‫ﻗﻴﻡ‬ ‫ﺘﺭﺍﻭﺤﺕ‬ ‫،ﺍﺫ‬ ‫ﻤﺎﺒﻴﻥ‬ ‫ﺍﻟﻤﻌﺎﻟﺠﺔ‬) 7,0 ‫ـ‬ 8,1 (‫ﻤﺎﺒﻴﻥ‬ ‫ﺘﺭﺍﻭﺤﺕ‬ ‫ﺍﺫ‬ ‫ﺍﻟﻤﻌﺎﻟﺠﺔ‬ ‫ﻋﻤﻠﻴﺔ‬ ‫ﺒﻌﺩ‬ ‫ﻗﻴﻤﺘﻬﺎ‬ ‫ﻤﻊ‬ ‫ﻤﻘﺎﺭﻨﺔ‬) 6,9 ‫ـ‬ 8,2 (‫ﻭﻗﻴﻡ‬ ‫ﺍﻟﻜﻬﺭﺒﺎﺌﻲ‬ ‫ﺍﻟﺘﻭﺼﻴل‬ ‫ﻤﺎﺒﻴﻥ‬ ‫ﺍﻟﻤﻌﺎﻟﺠﺔ‬ ‫ﻋﻤﻠﻴﺔ‬ ‫ﻗﺒل‬ ‫ﺘﺭﺍﻭﺤﺕ‬) 460 ‫ـ‬ 720 (‫ﻤﺎﻴﻜﺭﻭﻤﻭ‬ ‫ﺯ‬ / ‫ﻜﺎﻨﺕ‬ ‫ﺍﻟﻤﻌﺎﻟﺠﺔ‬ ‫ﻋﻤﻠﻴﺔ‬ ‫ﺒﻌﺩ‬ ‫ﺍﻤﺎ‬ ‫ﺴﻡ‬) 350 ‫ـ‬ 630 (‫ﻤﺎﻴﻜﺭﻭﻤﻭﺯ‬ / ،‫ﺴﻡ‬ ‫ﻓﺒﻠﻎ‬ ‫ﺍﻟﻜﻠﻴﺔ‬ ‫ﻟﻠﻌﺴﺭﺓ‬ ‫ﺒﺎﻟﻨﺴﺒﺔ‬ ‫ﺍﻤﺎ‬ ‫ﻤﻌﺩﻟ‬ ‫ﻬﺎ‬ ‫ﻗﺒل‬ ‫ﺍﻟﻤﻌﺎﻟﺠﺔ‬ ‫ﻋﻤﻠﻴﺔ‬) 233,8 (‫ﻤﻠﻐﻡ‬ / ‫ﻟﺘﺭ‬ ‫ﻤﻌﺩﻟﻬﺎ‬ ‫ﺍﻤﺎ‬ ‫ﺍﻟﻤﻌﺎﻟﺠﺔ‬ ‫ﻋﻤﻠﻴﺔ‬ ‫ﺒﻌﺩ‬) 238,6 (‫ﻤﻠﻐﻡ‬ / ‫ﻟﺘﺭ‬ ، ‫ﻤﺎﺒﻴﻥ‬ ‫ﻗﻴﻤﻬﺎ‬ ‫ﻓﺘﺭﺍﻭﺤﺕ‬ ‫ﺍﻟﻨﺘﺭﺍﺕ‬ ‫ﺍﻤﺎ‬) 0,403 ‫ـ‬ 1,341 (‫ﻤﻠ‬ ‫ﻐﻡ‬ / ‫ﺍﻟﻤﻌﺎ‬ ‫ﻋﻤﻠﻴﺔ‬ ‫ﻗﺒل‬ ‫ﻟﺘﺭ‬ ‫ﻭﺒﻴﻥ‬ ‫ﻟﺠﺔ‬) 0,47 ‫ـ‬ 1,423 (‫ﻤﻠﻐﻡ‬ / ‫ﻟﺘﺭ‬ ‫ﺍﻟﻤﻌﺎﻟﺠﺔ‬ ‫ﻋﻤﻠﻴﺔ‬ ‫ﺒﻌﺩ‬ ، ‫ﻟ‬ ‫ﻭﺒﺎﻟﻨﺴﺒﺔ‬ ‫ﻤﺎﺒﻴﻥ‬ ‫ﻗﻴﻤﻬﺎ‬ ‫ﺘﺭﺍﻭﺤﺕ‬ ‫ﻓﻘﺩ‬ ‫ﻠﻜﺒﺭﻴﺘﺎﺕ‬) 56,16-67,416 (‫ﻤﻠﻐﻡ‬ / ‫ﻤﻊ‬ ‫ﻤﻘﺎﺭﻨﺔ‬ ‫ﺍﻟﻤﻌﺎﻟﺠﺔ‬ ‫ﻋﻤﻠﻴﺔ‬ ‫ﻗﺒل‬ ‫ﻟﺘﺭ‬ ‫ﻤﺎﺒﻴﻥ‬ ‫ﺘﺭﺍﻭﺤﺕ‬ ‫ﻭﺍﻟﺘﻲ‬ ‫ﺍﻟﻤﻌﺎﻟﺠﺔ‬ ‫ﻋﻤﻠﻴﺔ‬ ‫ﺒﻌﺩ‬ ‫ﻗﻴﻤﻬﺎ‬) 55,33-69,83 (‫ﻤﻠﻐﻡ‬ / ،‫ﻟﺘﺭ‬ ‫ﻜﺎﻨﺕ‬ ‫ﺤﻴﻥ‬ ‫ﻓﻲ‬ ‫ﻗﻴﻡ‬ ‫ﺍﻟﺜﻘﻴﻠ‬ ‫ﺍﻟﻤﻌﺎﺩﻥ‬ ‫ﺘﺭﺍﻜﻴﺯ‬ ‫ﺔ‬ ‫ﻤﻥ‬ ‫ﻟﻜل‬ ‫ﻭﺍﻟﻨﺤﺎﺱ‬ ‫ﻭﺍﻟﻜﺎﺩﻤﻴﻭﻡ‬ ‫ﻭﺍﻟﻜﻭﺒﻠﺕ‬ ‫ﺍﻟﺭﺼﺎﺹ‬) 1,536 ‫ـ‬ 1,627 (،) 0,05793 ‫ـ‬ 0,06644 (،) 0,04794 ‫ـ‬ 0,04821 (،) 0,5378 ‫ـ‬ 0,5733 (‫ﻤﻠﻐﻡ‬ / ‫ﻟﺘﺭ‬ ‫ﻓﺒﻠﻐﺕ‬ ‫ﺍﻟﻤﻌﺎﻟﺠﺔ‬ ‫ﻋﻤﻠﻴﺔ‬ ‫ﺒﻌﺩ‬ ‫ﺘﺭﺍﻜﻴﺯﻫﺎ‬ ‫ﻗﻴﻡ‬ ‫ﺍﻤﺎ‬ ‫ﺍﻟﻤﻌﺎﻟﺠﺔ‬ ‫ﻋﻤﻠﻴﺔ‬ ‫ﻗﺒل‬ ‫ﺍﻟﺘﻭﺍﻟﻲ‬ ‫ﻋﻠﻰ‬) 1,324 ‫ـ‬ 1,410 (،) 0,06899 ‫ـ‬ 0,07814 (،) 0,04845 ‫ـ‬ 0,06227 (،) 0,5623 ‫ـ‬ 0,5825 (‫ﻤﻠﻐﻡ‬ / ‫ﻟﺘﺭ‬ ، ‫ﺍﻟﻌﺩﺩ‬ ‫ﻭﺼل‬ ‫ﺤﻴﻥ‬ ‫ﻓﻲ‬ ‫ﻤﺎﺒﻴﻥ‬ ‫ﺘﺭﺍﻭﺤﺕ‬ ‫ﻗﻴﻡ‬ ‫ﺍﻟﻰ‬ ‫ﻟﻠﺒﻜﺘﺭﻴﺎ‬ ‫ﺍﻟﻜﻠﻲ‬) 100 ‫ـ‬ 1100 (‫ﺨﻠﻴﺔ‬ / ‫ﺍﻟﻤﻌﺎﻟﺠﺔ‬ ‫ﻋﻤﻠﻴﺔ‬ ‫ﺒﻌﺩ‬ ‫ﻨﺘﺎﺌﺠﻬﺎ‬ ‫ﻤﻊ‬ ‫ﺒﺎﻟﻤﻘﺎﺭﻨﺔ‬ ‫ﺍﻟﻤﻌﺎﻟﺠﺔ‬ ‫ﻋﻤﻠﻴﺔ‬ ‫ﻗﺒل‬ ‫ﻤل‬ ‫ﻤﺎﺒﻴﻥ‬ ‫ﺘﺭﺍﻭﺤﺕ‬ ‫ﻭﺍﻟﺘﻲ‬) 300 ‫ـ‬ 3000 (‫ﺨﻠﻴﺔ‬ / ‫ﻤل‬. ‫ﺒﻴﻨ‬ ‫ﺍﺯﺍﻟ‬ ‫ﻓﻲ‬ ‫ﺍﻟﻤﻌﺎﻟﺠﺔ‬ ‫ﻤﺤﻁﺔ‬ ‫ﻜﻔﺎﺀﺓ‬ ‫ﻋﺩﻡ‬ ‫ﺍﻟﻨﺘﺎﺌﺞ‬ ‫ﺕ‬ ‫ﺍﻟﻤﻠﻭﺜﺎﺕ‬ ‫ﺔ‬. ‫ﺍﻟ‬ ‫ﺍﻟﻜﻠﻤﺎﺕ‬ ‫ﺩﺍﻟﺔ‬ : ،‫ﺍﻟﻤﻁﺭﻭﺤﺎﺕ‬ ‫ﻤﻌﺎﻟﺠﺔ‬ ‫ﻤﺤﻁﺔ‬ ،‫ﺍﻟﻘﻴﺎﺭﺓ‬ ‫ﻤﺼﻔﻰ‬ ‫ﺍﻟﻤﻠﻭﺜﺎﺕ‬. ‫ــــــــــــــــــــــــــــــ‬ ‫ـ‬ ‫ــــــــــــــــــــــــــــــــــ‬ ABSTRACT The study was accomplished for the evaluation of the efficiency of the processing station of excretion in Al-Qayyarah refinery, which is located in the area of Al-Qayyarah town toward the south east direction of Mosul city / Iraq. For this purpose, monthly samples were collected for five