Halogenation Using Quaternary Ammonium Polyhalides. VII. Iodination of Aromatic Amines by Use of Benzyltrimethylammonium Dichloroiodate(1—)

  • Kajigaeshi S
  • Kakinami T
  • Yamasaki H
  • et al.
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Abstract

The reaction of aromatic amines with benzyltrimethylammonium dichloroiodate(1—) in dichloromethane–methanol in the presence of calcium carbonate powder for several hours at room temperature gave selectively iodosubstituted aromatic amines in good yields.

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Kajigaeshi, S., Kakinami, T., Yamasaki, H., Fujisaki, S., & Okamoto, T. (1988). Halogenation Using Quaternary Ammonium Polyhalides. VII. Iodination of Aromatic Amines by Use of Benzyltrimethylammonium Dichloroiodate(1—). Bulletin of the Chemical Society of Japan, 61(2), 600–602. https://doi.org/10.1246/bcsj.61.600

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