Abstract
EPR spectroscopy and theoretical data show that the slow heterogeneous electron-transfer kinetics associated with the reduction of an 18-electron Mo(iv) acetato dihydride are a consequence of an η2-η1 rearrangement of the carboxylate ligand which gives a unique paramagnetic 17-electron Mo(iii) dihydride.
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CITATION STYLE
APA
Prior, C., Webster, L. R., Ibrahim, S. K., Wright, J. A., Alghamdi, A. F., Oganesyan, V. S., & Pickett, C. J. (2016). EPR detection and characterisation of a paramagnetic Mo(III) dihydride intermediate involved in electrocatalytic hydrogen evolution. Dalton Transactions, 45(6), 2399–2403. https://doi.org/10.1039/c5dt04432d
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