Abstract
Convenient syntheses of “chelated heme” compounds from naturally occurring hemes are described. NMR studies of the carbon monoxide complex of chelated protoheme serve to characterize this model compound in solution. Chelated protoheme, having a “proximal” imidazole covalently attached, displays spectra and kinetics and equilibria of reaction with dioxygen and carbon monoxide that are similar to those of R-state hemoglobin, making chelated protoheme unique among model compounds. © 1979, American Chemical Society. All rights reserved.
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CITATION STYLE
Traylor, T. G., Chang, C. K., Geibel, J., Berzinis, A., Mincey, T., & Cannon, J. (1979). Syntheses and NMR Characterization of Chelated Heme Models of Hemoproteins. Journal of the American Chemical Society, 101(22), 6716–6731. https://doi.org/10.1021/ja00516a038
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