Operando synthesis of high-curvature copper thin films for CO 2 electroreduction

Abstract

As the sole metal that could reduce CO 2 to substantial amounts of hydrocarbons, Cu plays an important role in electrochemical CO 2 reduction, despite its low energy efficiency. Surface morphology modification is an effective method to improve its reaction activity and selectivity. Different from the pretreated modification method, in which the catalysts self-reconstruction process was ignored, we present operando synthesis by simultaneous electro-dissolution and electro-redeposition of copper during the CO 2 electroreduction process. Through controlling the cathodic potential and CO 2 flow rate, various high-curvature morphologies including microclusters, microspheres, nanoneedles, and nanowhiskers have been obtained, for which the real-time activity and product distribution is analyzed. The best CO 2 electro-reduction activity and favored C 2 H 4 generation activity, with around 10% faradic efficiency, can be realized through extensively distributed copper nanowhiskers synthesized under 40 mL/min flow rate and -2.1 V potential.